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Detailed simulations of the glass transition 7. Comprehensive list of factors determining T 8. Outline of remainder of this chapter B. Correlation for the glass transition temperature 1. Outline 2. The structural parameters 3. The correlation C. Effects of number-average molecular weight D. Effects of plasticization E. Effects of crosslinking 1. A correlation 2.
Other developments F. Effects of tacticity G. Secondary relaxations H. Crystalline melting temperature 1. Homopolymers 2. Copolymers and crosslinked polymers I. Roles of Tg and Tm in determining the crystallization kinetics 1. Overall rate for isothermal crystallization 3. Overall rate for non-isothermal crystallization 4.
Nucleation 5. Isothermal crystal growth rate from existing nuclei References and notes for Chapter 6. Chapter 7. Surface Tension and Interfacial Tension A. Surf ace tension 1. Total surf ace tension 2.
- Prediction of Polymer Properties?
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Components of surface tension. XIV Contents. Interfacial tension C. Adhesion D. Improvements in the ability to predict surface tension and interfacial tension E.
Approximate "master curve" as a function of reduced temperature F. Correlation for the molar parachor G. Frontiers of interfacial modeling References and notes for Chapter 7. Chapter 8.
Prediction of Polymer Properties (Plastics Engineering)
Optical Properties A. Types of optical properties 2. Refractive index and molar refraction 3. Optical losses 4. Stress-optic coefficient B. Improvements in the ability to predict the refractive i ndices of polymers C. Correlation for the refractive index at room temperature D. Example of application: specific refractive index increments of solutions E. Calculation of the molar refraction References and notes for Chapter 8. Chapter 9.
Electrical Properties A. Background information B. Correlation for the dielectric constant at room temperature C. Calculation of the molar polarization D. Calculation of the effective dipole moment E.
Dissipation factor F. Dielectric strength References and notes for Chapter 9. Chapter Magnetic Properties A.
Correlation for the molar diamagnetic susceptibility References and notes for Chapter Contents XV. Small-strain behavior: moduli, compliances, and Poisson's ratio 1. Structure-property relationships for glassy polymers a.
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Introductory remarks b. Correlations by Seitz for the elastic moduli c. Bulk modulus via molar Rao function d. Shear modulus via molar Hartmann function e. Thermosets 3. Structure-property relationships for rubbery polymers a. Shear modulus b.
A graph-structural method for prediction of polymer properties
Bulk modulus and Young's modulus 4. Effects of anisotropy orientation C. Large-strain behavior: failure mechanisms 1. Phenomenology a. General mechanisms b. Toughening by incorporating another phase 2. Structure-property relationships for the brittle fracture stress 3. Structure-property relationships for the yield stress of thermoplastics 4.
Attempts to model rate dependence of yield stress of thermoplastics 5. Structure-property relationships for the crazing stress 6. Stress-strain curves of elastomers 7.